Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.
A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework
CARNIATO, FABIO;TEI, LORENZO;BOTTA, Mauro;
2015-01-01
Abstract
Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.File in questo prodotto:
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Dalton Trans., 2015,44, 19072-19075.pdf
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