1 Contributo su Rivista

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L’apport académique du recueil au-delà du droit international privé

Il diritto internazionale privato non può essere separato dal diritto comparato. Al di là della ricera del diritto straniero applicabile (che costituisce un soggetto di studio autonomo), il diritto comparato ricorda che ogni legislatore si rivolge ai giuristi del proprio sistema: utilizza convenzioni linguistiche, riferimenti impliciti a schemi concettuali che sono loro propri; nasconde nel non detto elementi che sembrano evidenti al giurista nazionale, ma che scompaiono agli occhi del giuri...

CCII: una lettura ‘di sistema’ e qualche considerazione praeter codicem

Il contributo, dopo aver brevemente ricordato le principali modifiche apportate dal d.lgs. n. 136/2024 al d.lgs. n. 14/2019 al fine di razionalizzare e riordinare la disciplina codicistica della crisi di impresa e dell’insolvenza, s’interroga sui residui spazi vuoti e cerca di ricostruire in via interpretativa le tessere mancanti.

Aerobic Oxidation of Alkylaromatics using a LipophilicN-Hydroxyphthalimide: Overcoming the Industrial Limit of Catalyst Solubility

4,4’-(4,4’-Isopropylidenediphenoxy)bis(N-hydroxyphthalimide), which is a new lipophilic analogue of N-hydroxyphthalimide, can act as an effective catalyst in the aerobic oxidation of alkylaromatics under reduced amounts of polar cosolvent. The catalyst was selected on the basis of an in-depth study of the influence that substituents on the aromatic ring of N-hydroxyphthalimide exert on determining the NO H bond dissociation energy (BDE). BDE values for a range of model molecules are calcula...

Functionalization of Cyclodextrins with N-Hydroxyphthalimide Moiety: A New Class of Supramolecular Pro-Oxidant Organocatalysts

N-hydroxyphthalimide (NHPI) is an organocatalyst for free-radical processes able to promote the aerobic oxidation of a wide range of organic substrates. In particular, NHPI can catalyze the hydroperoxidation of polyunsaturated fatty acids (PUFA). This property could be of interest for biological applications. This work reports the synthesis of two β-cyclodextrin derivatives (CD5 and CD6) having a different degree of methylation and bearing a NHPI moiety. These compounds, having different solu...

Mixed Stacked Charge-Transfer π-Organic Materials Based on Anthracenyl Boronic Acid

Anthracenyl boronic acid derivatives are used for the first time as hydrogen-bond and π-donors to obtain a series of novel 1:1 mixed stacked π-organic materials with interesting structural, UV/Vis reflectance and emission properties by reaction with quinones in both solution and the solid. The underlying principles, which have led to hetero-assembly, could be applied to construct a potentially large variety of mixed stacked π-organic solid-state materials for technological applications.

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