Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).
Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes
IMPERIO D;GIOVENZANA, Giovanni Battista;
2010-01-01
Abstract
Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
Dalton-AAZX-PTDITA.pdf
file disponibile solo agli amministratori
Tipologia:
Altro materiale allegato
Licenza:
DRM non definito
Dimensione
1.54 MB
Formato
Adobe PDF
|
1.54 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
