An overview of the different strategies proposed for the preparation of heterolanthanide assemblies suitable to work as (multi-) functional materials, highlighting their structure/property relationship, is provided. Three classes of compounds are selected: multi-dimensional coordination frameworks, polynuclear discrete molecules and flexible large molecules formed by two or more coordinating units connected by a linker. Synthetic approaches and potential functionalities are discussed on the basis of lanthanide ion discrimination and the structural arrangement of the heterometallic assembly.
Tailoring functionality through synthetic strategy in heterolanthanide assemblies
Artizzu F
Primo
;
2015-01-01
Abstract
An overview of the different strategies proposed for the preparation of heterolanthanide assemblies suitable to work as (multi-) functional materials, highlighting their structure/property relationship, is provided. Three classes of compounds are selected: multi-dimensional coordination frameworks, polynuclear discrete molecules and flexible large molecules formed by two or more coordinating units connected by a linker. Synthetic approaches and potential functionalities are discussed on the basis of lanthanide ion discrimination and the structural arrangement of the heterometallic assembly.File in questo prodotto:
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