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Synthesis of stable ruthenium carbonyl complexes containing alkynols ligands and 2(diphenylphosphino)ethyl-triethoxysilane: novel complexes to anchor on mesoporous silica SBA-15 and Al2O3 surface
2011-01-01 Secco, Andrea; Carniato, Fabio; Gatti, Giorgio; Marabello, D; Sappa, Enrico
Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica
2010-01-01 Carniato, Fabio; Gatti, Giorgio; Gervasio, G; Marabello, D; Sappa, Enrico; Secco, Andrea
Reactions of Co2(CO)8 and of Co2(CO)6L (L= 3-pentyn-1-ol, 1,4-butyin-diol or 2-methyl-3-butyn-2-ol) with 2(diphemylphosphino)ethyl-trietoxysilane and tris(hydroxymethyl)phosphine for applications to new sol-gel materials
2009-01-01 Carniato, Fabio; G., Gatti; G., Gervasio; D., Marabello; Sappa, Enrico; A., Secco
Reactions of Co2(CO)8 and of Co2(CO)6L (L = 3-pentyn-1-ol, 1,4-butyn-diol or 2-methyl-3-butyn-2-ol) with 2(diphenylphosphino)ethyl-trietoxysilane and tris(hydroxymethyl)phosphine for applications to new sol–gel materials
2009-01-01 Carniato, Fabio; Gatti, Giorgio; Gervasio, G; Marabello, D; Sappa, Enrico; Secco, Andrea
Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas
2009-01-01 Carniato, Fabio; Secco, Andrea; Gatti, Giorgio; Marchese, Leonardo; Sappa, Enrico
Unexpected carbon-carbon bond cleavage in the reactions of the pentagonal bipyramidal cluster Fe3(CO)6(CO)2[(EtC2R)]2 (R=CH3(=CH2))
2008-01-01 Gervasio, G; Marabello, D; Sappa, Enrico; Secco, A.
Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions. The crystal structures of Fe2(CO)6(CO)[HCC(=CH3)2]C(=O)(OCH3) and of HFe3(CO)9[H3CCC(CH2)(CH2)CO]
2008-01-01 Bertolotti, F; Gervasio, G; Marabello, D; Sappa, Enrico; Secco, A.
Carbon-carbon bond forming and cleavage in the reactions of isopropenylacetylene and 2-methyl-1-hex-en-3-yne with Fe3(CO)12 in basic methanolic solution. The X-ray structure of Fe2(CI)5[RCC(H)C(CH3)CR] (R=CH3=CH2))
2008-01-01 Gervasio, G; Marabello, D; Sappa, Enrico; Secco, A.
The reactions of two new alkoxy-silyl functionalized alkynes with M3(CO)12 (M=Fe,Ru) and Co2(CO)8. Spectroscopic identification of the products
2007-01-01 Arrais, Aldo; Sappa, Enrico; Secco, Andrea
Reactions of Ru3(CO)12 with ene-yne and alkoxy-silyl functionalozed compounds. The cristal structure of HRu3(CO)9[HC=N(CH2)3SiOEt)3
2007-01-01 Gervasio, G; Marabello, D; Sappa, Enrico; Secco, A.
Reactions of Fe3(CO)12 and Fe(CO)5 with functionalized alkynes in CH3OH/KOH solution. The crystal structure of Fe2(CO)6(PPh3)[H2CCCH2]
2006-01-01 Gervasio, G; Marabello, D; Sappa, Enrico; Secco, A.
Trinuclear clusters of Ruthenium and Osmium: compounds containing M-C bonds to heteroatom ligands
2006-01-01 Sappa, Enrico
Iron cluster compounds: compounds with Fe-C bonds to heteroatom ligands
2006-01-01 Sappa, Enrico
Reactions of Co2(CO)6(RCCR') (RCCR' -hydroxy or -alkoxysilyl alkynes) with tetraethyl-orthosilicate
2006-01-01 Arrais, Aldo; Boccaleri, Enrico; Sappa, Enrico; Secco, Andrea
The reaction of Ru3(CO)12 with 1,4-dichloro-but-2-yne in basic methanolic solution. Synthesis and crystal structure of (μ-H)2Ru3(CO)9{μ3-η2-[H2C=C(H)C≡CC(=O)OCH3]}
2005-01-01 Gervasio, G.; Marabello, D.; Sappa, Enrico; Secco, A.
Reactions of Ru3(CO)12 with 2-pentynal-diethyl-acetal. The crystal structure of Ru2(CO)6[μ- η4-{EtC2C(H)(OEt)2}CO{EtC2C(H)(OEt)2}] and its reactivity towards tetraethyl-orthosilicate
2005-01-01 Gervasio, G.; Marabello, D.; Sappa, Enrico; Secco, A.
Reaction of Fe3(CO)12 with but-2-yn-1,4-diol, 1,4-dichloro-but-2-yne, propargyl alcohol and propargyl chloride. The X-ray structures of Fe2(CO)6{H2CCCCH2}, Fe2(CO)6{H2CCC(H)C(OCH3)O} and Fe3(CO)10{H2CCC(H)C(O)C[CH2(O)CH3]CCH3}
2005-01-01 Gervasio, G.; Marabello, D.; Sappa, Enrico; Secco, A.
Reactions of Ru3(CO)12 with but-2-yn-1,4-diol in CH3OH/KOH solution. Crystal structure of (μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2]
2004-01-01 Gervasio, G.; Marabello, D.; Sappa, Enrico; Secco, A.
Transition metal carbonyl clusters with ene-yne ligands
2003-01-01 G., Gervasio; P. J., King; D., Marabello; Sappa, Enrico
Reactions of diphenylacetylene and dihydrogen with chalcogenide- or mehylidyne-capped trinuclear iron, ruthenium and cobalt clusters. Evidence for the formation and recombination of metal fragments
2003-01-01 C., Allasia; M., Castiglioni; G., Predieri; Sappa, Enrico
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